Issue 14, 2004
From the journal:

Dalton Transactions

Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes†

Andrea Berenbauma  and  Ian Manners*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: imanners@chem.utoronto.ca

Abstract

Silicon-bridged bis(benzene)chromium complexes (sila[1]chromarenophanes) undergo facile transition metal-catalyzed ROP at ambient temperature in the presence of Karstedt's catalyst to yield polychromarenylsilanes, the first homopolymers with main chains of Cr(arene)2 and organosilane units.

Graphical abstract: Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes

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Article information

DOI
https://doi.org/10.1039/B406873D
Article type
Communication
Submitted
07 May 2004
Accepted
04 Jun 2004
First published
21 Jun 2004

Dalton Trans., 2004, 2057-2058

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Transition metal-catalyzed ring-opening polymerization (ROP) of strained, silicon-bridged bis(benzene)chromium complexes

A. Berenbaum and I. Manners, Dalton Trans., 2004, 2057 DOI: 10.1039/B406873D

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