Issue 14, 2004
From the journal:

Dalton Transactions

A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42−

Felipe García,a   Alexander D. Hopkins,*a   Richard A. Kowenicki,a   Mary McPartlinb  and  Yolanda Tesaa  

* Corresponding authors

a Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: adh1002@cam.ac.uk
Fax: 44 1223 336362
Tel: 44 1223 763122

b Department of Health & Biological Sciences, London Metropolitan University, Holloway Road, London, UK

Abstract

The reaction of (Me3Si)3SiK·18-crown-6 with SbCl3 (3 : 1 equiv.) provides a simple route to the title complex [(Me3Si)3SiSb]4. The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb–Sb bonds.

Graphical abstract: A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42−

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Article information

DOI
https://doi.org/10.1039/B405032K
Article type
Communication
Submitted
05 Apr 2004
Accepted
25 May 2004
First published
03 Jun 2004

Dalton Trans., 2004, 2051-2052

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A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42−

F. García, A. D. Hopkins, R. A. Kowenicki, M. McPartlin and Y. Tesa, Dalton Trans., 2004, 2051 DOI: 10.1039/B405032K

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