Issue 9, 2004
From the journal:

Dalton Transactions

Anionic triazine systems†

Melanie Kingston,a   Shan-Jia Chen,a   Enno Lorka  and  Rüdiger Mews*a  

* Corresponding authors

a Institut für Anorganische und Physikalische Chemie der Universität Bremen, Postfach 330440, Leobener Straße, 28334 Bremen, Germany
E-mail: mews@chemie.uni-bremen.de

Abstract

The synthesis of TAS+C3N3F4− (1) (TAS+ = (Me2N)3S+) and the reactions of 1 with Me3SiOSiMe3 and Me3SiCF3 to give TAS+C3N3F2O− (2) and TAS+[(NCF)(NCCF3)(NC(CF3)2]− (4) are reported. An isomer of 4, TAS+[(NCCF3)2(NCFCF3)]−, compound 6, was obtained by fluoride ion addition to (CF3CN)3. From the reactions with Me3SiNMe2 neutral fluoroamino triazines C3N3Fn(NMe2)n−1 (n = 1, 2) were isolated. Possible reaction pathways are discussed, the X-ray structures of 1, 2, 4 and 6 were determined.

Graphical abstract: Anionic triazine systems

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Article information

DOI
https://doi.org/10.1039/B402527J
Article type
Paper
Submitted
18 Feb 2004
Accepted
22 Mar 2004
First published
05 Apr 2004

Dalton Trans., 2004, 1400-1404

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Anionic triazine systems

M. Kingston, S. Chen, E. Lork and R. Mews, Dalton Trans., 2004, 1400 DOI: 10.1039/B402527J

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