Perfluoroalkylphosphine coordination chemistry of platinum: synthesis of (C2F5)2PPh and (C2F5)PPh2 complexes of platinum(ii)
Abstract
A 1 ∶ 1 addition of Ph2PCl to an ethereal solution of C2F5Li (formed from the reaction of BuLi with C2F5Cl) yields Ph2P(C2F5)
(abbreviated pfepp) (1). The introduction of a fluoroethyl group results in a