Issue 3, 2004

Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane

Abstract

The title compound was synthesised in moderate yield via stereoselective self-assembly of two bisphosphine, four formaldehyde and two primary amine molecules.

Graphical abstract: Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane

Supplementary files

Article information

Article type
Communication
Submitted
24 Oct 2003
Accepted
16 Dec 2003
First published
06 Jan 2004

Dalton Trans., 2004, 357-358

Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane

R. N. Naumov, A. A. Karasik, O. G. Sinyashin, P. Lönnecke and E. Hey-Hawkins, Dalton Trans., 2004, 357 DOI: 10.1039/B313487C

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