Issue 13, 2004

Internal rotation in the para-difluorobenzene–nitrogen van der Waals complex

Abstract

Barriers hindering internal rotation in the para-difluorobenzene–nitrogen complex have been obtained by fitting experimental transition frequencies from a rotationally resolved UV spectrum using a semirigid C2v top–C2v frame internal rotation model. In both electronic states, the barrier has been found to be very low, with upper limits of 20 and 6 cm−1 for S0 and S1, respectively.

Article information

Article type
Paper
Submitted
26 Jan 2004
Accepted
18 Mar 2004
First published
24 May 2004

Phys. Chem. Chem. Phys., 2004,6, 3271-3279

Internal rotation in the para-difluorobenzene–nitrogen van der Waals complex

M. Schäfer, Phys. Chem. Chem. Phys., 2004, 6, 3271 DOI: 10.1039/B401230P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements