Issue 5, 2004
From the journal:

Physical Chemistry Chemical Physics

Raman study of crystalline solvates between glymes CH3(OCH2CH2)nOCH3 (n = 1, 2 and 3) and LiClO4

Joseph Grondin,a   David Talaga,a   Jean-Claude Lassègues*a  and  Wesley A. Hendersonb  

* Corresponding authors

a Laboratoire de Physico-Chimie Moléculaire, UMR 5803 CNRS, Université Bordeaux I, 351 Cours de la Libération, Talence, France
E-mail: jc.lassegues@lpcm.u-bordeaux1.fr
Fax: 33 5 56 84 84 02
Tel: 33 5 56 84 63 55

b Department of Chemical Engineering & Materials Science, University of Minnesota, Minneapolis, Minnesota, USA

Abstract

The Raman spectra of various crystalline complexes formed between LiClO4 and poly(ethylene glycol) dimethyl ether oligomers CH3(OCH2CH2)nOCH3 with n = 1, 2 and 3 have been investigated in order to establish a clear vibrational assignment for the anion involved in typical solvent-separated ion pair, contact ion pair (with monodentate or bidentate coordination to the cation) and aggregate solvates. The Raman spectrum of the pure LiClO4 salt has also been recorded for comparison.

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Article information

DOI
https://doi.org/10.1039/B315475K
Article type
Paper
Submitted
01 Dec 2003
Accepted
12 Jan 2004
First published
04 Feb 2004

Phys. Chem. Chem. Phys., 2004,6, 938-944

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Raman study of crystalline solvates between glymes CH3(OCH2CH2)nOCH3 (n = 1, 2 and 3) and LiClO4

J. Grondin, D. Talaga, J. Lassègues and W. A. Henderson, Phys. Chem. Chem. Phys., 2004, 6, 938 DOI: 10.1039/B315475K

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