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Issue 96, 2004

2D Layered coordination polymer based on an unusual mixed valence Cu(iii)/Cu(i) bis-1,2-diselenolene compound

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Abstract

The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds2− (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [CuIII(pds)2] complex, with a distorted square pyramidal environment for Cu(I) centres.

Graphical abstract: 2D Layered coordination polymer based on an unusual mixed valence Cu(iii)/Cu(i) bis-1,2-diselenolene compound

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Article information


Submitted
05 Oct 2004
Accepted
25 Oct 2004
First published
02 Nov 2004

CrystEngComm, 2004,6, 589-592
Article type
Communication

2D Layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

X. Ribas, D. Maspoch, J. Dias, J. Morgado, M. Almeida, K. Wurst, G. Vaughan, J. Veciana and C. Rovira, CrystEngComm, 2004, 6, 589
DOI: 10.1039/B415416A

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