Issue 96, 2004
From the journal:

CrystEngComm

2D Layered coordination polymer based on an unusual mixed valence Cu(iii)/Cu(i) bis-1,2-diselenolene compound

Xavi Ribas,a   Daniel Maspoch,a   João Dias,b   Jorge Morgado,bc   Manuel Almeida,b   Klaus Wurst,d   Gavin Vaughan,e   Jaume Vecianaa  and  Concepció Rovira*a  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona, CSIC, Campus de la UAB, E-08193 Bellaterra, Spain
E-mail: cun@icmab.es

b Departamento de Química, Instituto Tecnológico e Nuclear/CFMCUL, P-2686-953 Sacavém, Portugal

c Departamento Engenharia Química, Instituto Superior Tecnico, Av. Rovisco Pais, P-1049-001 Lisboa, Portugal

d Institut für Allgemeine, Anorganische und Theoretische Chemie, Universitat Innsbruck, Innrain 52a, Innsbruck, Austria

e European Synchrotron Radiation Facility(E.S.R.F.), B.P. 220, 38043 Grenoble cedex, France

Abstract

The crystal structure of a new mixed-valence Cu(III)/Cu(I) compound containing the ligand pds2− (pds, pyrazine-2,3-diselenolate) shows a unique packing pattern with 2D layers formed by the coordination of the Cu(I) countercations to both the pyrazine N and Se atoms of the [CuIII(pds)2]− complex, with a distorted square pyramidal environment for Cu(I) centres.

Graphical abstract: 2D Layered coordination polymer based on an unusual mixed valence Cu(iii)/Cu(i) bis-1,2-diselenolene compound

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Article information

DOI
https://doi.org/10.1039/B415416A
Article type
Communication
Submitted
05 Oct 2004
Accepted
25 Oct 2004
First published
02 Nov 2004

CrystEngComm, 2004,6, 589-592

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2D Layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound

X. Ribas, D. Maspoch, J. Dias, J. Morgado, M. Almeida, K. Wurst, G. Vaughan, J. Veciana and C. Rovira, CrystEngComm, 2004, 6, 589 DOI: 10.1039/B415416A

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