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Issue 19, 2004
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Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes

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Abstract

The reaction of an imidazolium salt with LiBEt3H afforded triethylborane adduct of imidazol-2-ylidene, which can act as a carbene precursor for the synthesis of a transition metal complex as well as a main group element complex.

Graphical abstract: Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes

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Publication details

The article was received on 14 Apr 2004, accepted on 05 Jul 2004 and first published on 20 Aug 2004


Article type: Communication
DOI: 10.1039/B405459H
Chem. Commun., 2004, 2160-2161

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    Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes

    Y. Yamaguchi, T. Kashiwabara, K. Ogata, Y. Miura, Y. Nakamura, K. Kobayashi and T. Ito, Chem. Commun., 2004, 2160
    DOI: 10.1039/B405459H

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