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Issue 10, 2004
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A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

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Abstract

The reaction of a 3-connecting PTMTC radical and a 2-connecting 4,4′-bipyridine ligands with Co(MeCOO)2·4H2O forms a paramagnetic non-interpenetrated supramolecular network, Co(PTMTC)(4,4′-bpy)(H2O)3·6EtOH·2H2O (MOROF-2), with an unprecedented (63)·(69.81) topology exhibiting helical nanochannels.

Graphical abstract: A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

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Article information


Submitted
24 Nov 2003
Accepted
31 Mar 2004
First published
22 Apr 2004

Chem. Commun., 2004, 1164-1165
Article type
Communication

A new (63)·(69.81) non-interpenetrated paramagnetic network with helical nanochannels based on a tricarboxylic perchlorotriphenylmethyl radical

D. Maspoch, D. Ruiz-Molina, K. Wurst, C. Rovira and J. Veciana, Chem. Commun., 2004, 1164
DOI: 10.1039/B315147F

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