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Issue 5, 2004
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Cooperative C–F⋯Si interaction in optically active helical polysilanes

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Abstract

Cooperative amplification of the C–F⋯Si weak interaction between side chains and the main chain was found to afford rigid rodlike helical polysilanes with a preferential screw sense.

Graphical abstract: Cooperative C–F⋯Si interaction in optically active helical polysilanes

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Article information


Submitted
14 Nov 2003
Accepted
24 Dec 2003
First published
27 Jan 2004

Chem. Commun., 2004, 538-539
Article type
Communication

Cooperative C–F⋯Si interaction in optically active helical polysilanes

S. Kim, A. Saxena, G. Kwak, M. Fujiki and Y. Kawakami, Chem. Commun., 2004, 538
DOI: 10.1039/B314723A

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