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Issue 2, 2004
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Atropisomers and near-atropisomers: achieving stereoselectivity by exploiting the conformational preferences of aromatic amides

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Abstract

The conformational preferences of aromatic amides are remarkably easy to control with a high degree of selectivity. This article reviews the consequences of this unusual form of stereocontrol, which enables for example the asymmetric synthesis of atropisomers and the ability to achieve remote stereocontrol by conformational relay.

Graphical abstract: Atropisomers and near-atropisomers: achieving stereoselectivity by exploiting the conformational preferences of aromatic amides

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Publication details

The article was received on 11 Jul 2003, accepted on 04 Sep 2003 and first published on 14 Oct 2003


Article type: Feature Article
DOI: 10.1039/B307976G
Citation: Chem. Commun., 2004,0, 127-135
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    Atropisomers and near-atropisomers: achieving stereoselectivity by exploiting the conformational preferences of aromatic amides

    J. Clayden, Chem. Commun., 2004, 0, 127
    DOI: 10.1039/B307976G

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