Issue 22, 2004
From the journal:

Chemical Communications

Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv)[double bond, length as m-dash]O species†

Tieme A. van den Berg,a   Johannes W. de Boer,a   Wesley R. Browne,a   Gerard Roelfesa  and  Ben L. Feringa*a  

* Corresponding authors

a Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, Groningen, The Netherlands
E-mail: Feringa@chem.rug.nl
Fax: +31 50 3634296
Tel: +31 50 3634235

Abstract

Catalytic alkane oxidation with high selectivity using peracids and an (N4Py)Fe complex is presented and the role of [(N4Py)Fe(IV)[double bond, length as m-dash]O]2+ species, molecular oxygen and hydroxyl radicals in the catalysis is discussed.

Graphical abstract: Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(iv) [[double bond, length as m-dash]] O species

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Article information

DOI
https://doi.org/10.1039/B412016G
Article type
Communication
Submitted
05 Aug 2004
Accepted
14 Sep 2004
First published
14 Oct 2004

Chem. Commun., 2004, 2550-2551

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Enhanced selectivity in non-heme iron catalysed oxidation of alkanes with peracids: evidence for involvement of Fe(IV)[double bond, length as m-dash]O species

T. A. van den Berg, J. W. de Boer, W. R. Browne, G. Roelfes and B. L. Feringa, Chem. Commun., 2004, 2550 DOI: 10.1039/B412016G

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