Issue 23, 2004
From the journal:

Chemical Communications

Adduct formation by photo-induced electron transfer between photo-oxidising Ru(ii) complexes and tryptophan†

Etienne Gicquel,a   Arnaud Boisdenghien,a   Eric Defrancq,b   Cécile Moucherona  and  Andrée Kirsch-De Mesmaeker*a  

* Corresponding authors

a Laboratoire de Chimie Organique et Photochimie, Université Libre de Bruxelles, 50 Av. F.D. Roosevelt, Bruxelles, Belgique
E-mail: akirsch@ulb.ac.be
Fax: (+32)2 650 3018
Tel: (+32)2 650 3017

b LEDSS, UMR5616, Université Joseph Fourier, Grenoble, France

Abstract

The 3MLCT excited state of Ru(II) complexes with 1,4,5,8-tetraazaphenanthrene (TAP) ligands in the presence of tryptophan gives rise to an electron transfer process from the amino acid with subsequent formation of an adduct between the two partners, strongly influenced by oxygen.

Graphical abstract: Adduct formation by photo-induced electron transfer between photo-oxidising Ru(ii) complexes and tryptophan

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Article information

DOI
https://doi.org/10.1039/B411686K
Article type
Communication
Submitted
30 Jul 2004
Accepted
16 Sep 2004
First published
21 Oct 2004

Chem. Commun., 2004, 2764-2765

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Adduct formation by photo-induced electron transfer between photo-oxidising Ru(II) complexes and tryptophan

E. Gicquel, A. Boisdenghien, E. Defrancq, C. Moucheron and A. K. Mesmaeker, Chem. Commun., 2004, 2764 DOI: 10.1039/B411686K

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