Issue 24, 2004
From the journal:

Chemical Communications

Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

Chrétien Simons,ab   Ulf Hanefeld,b   Isabel W. C. E. Arends,a   Adriaan J. Minnaard,c   Thomas Maschmeyer†*b  and  Roger A. Sheldon*a  

* Corresponding authors

a Laboratory for Biocatalysis and Organic Chemistry, Department of Biotechnology, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands
E-mail: R.A.Sheldon@tnw.tudelft.nl
Fax: (+31)-15-2781415

b Laboratory for Applied Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands

c Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands

Abstract

Rhodium-MonoPhos was successfully immobilised by ionic interactions on aluminosilicate AlTUD-1. The resulting new heterogeneous catalyst can be used in water and showed excellent enantioselectivity and activity in the asymmetric hydrogenation of methyl-2-acetamidoacrylate.

Graphical abstract: Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

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Article information

DOI
https://doi.org/10.1039/B411506F
Article type
Communication
Submitted
28 Jul 2004
Accepted
15 Sep 2004
First published
26 Oct 2004

Chem. Commun., 2004, 2830-2831

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Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1

C. Simons, U. Hanefeld, I. W. C. E. Arends, A. J. Minnaard, T. Maschmeyer and R. A. Sheldon, Chem. Commun., 2004, 2830 DOI: 10.1039/B411506F

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