Issue 23, 2004
From the journal:

Chemical Communications

Synthesis of C-arylglycosides via Ru(ii)-catalyzed [2 + 2 + 2] cycloaddition

Yoshihiko Yamamoto,*a   Tomoaki Saigoku,a   Takashige Ohgai,b   Hisao Nishiyamaa  and  Kenji Itohb  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan
E-mail: yamamoto@apchem.nagoya-u.ac.jp
Fax: 81 52 789 3209
Tel: 81 52 789 3337

b Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Japan

Abstract

In the presence of catalytic amounts of Cp*RuCl(cod), the cycloaddition of 1,6-diynes with various C-alkynylglycosides proceeded at ambient temperature to afford C-arylglycosides in 46–93% yields.

Graphical abstract: Synthesis of C-arylglycosides via Ru(ii)-catalyzed [2 + 2 + 2] cycloaddition

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Article information

DOI
https://doi.org/10.1039/B411442F
Article type
Communication
Submitted
28 Jul 2004
Accepted
22 Sep 2004
First published
07 Oct 2004

Chem. Commun., 2004, 2702-2703

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Synthesis of C-arylglycosides via Ru(II)-catalyzed [2 + 2 + 2] cycloaddition

Y. Yamamoto, T. Saigoku, T. Ohgai, H. Nishiyama and K. Itoh, Chem. Commun., 2004, 2702 DOI: 10.1039/B411442F

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