Structurally diverse Rh(I) and Mn(I) complexes derived from the new ambidentate indene ligand, (1-{iPr2P(S)}-2-{NMe2})C9H6

Dominik Wechsler; Robert McDonald; Michael J. Ferguson; Mark Stradiotto

doi:10.1039/B410328A

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Structurally diverse Rh(i) and Mn(i) complexes derived from the new ambidentate indeneligand, (1-{ⁱPr₂P(S)}-2-{NMe₂})C₉H₆†

Dominik Wechsler,^a Robert McDonald,^b Michael J. Ferguson^b and Mark Stradiotto*^a

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* Corresponding authors

^a Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada
E-mail: mark.stradiotto@dal.ca
Fax: 1-902-494-1310
Tel: 1-902-494-7190

^b X-Ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada

Abstract

A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a κ²-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in κ²-[C,S] and η⁵ modes, respectively.

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Article information

DOI: https://doi.org/10.1039/B410328A
Article type: Communication
Submitted: 08 Jul 2004
Accepted: 17 Aug 2004
First published: 21 Sep 2004

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Chem. Commun., 2004, 2446-2447

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Structurally diverse Rh(I) and Mn(I) complexes derived from the new ambidentate indene ligand, (1-{ⁱPr₂P(S)}-2-{NMe₂})C₉H₆

D. Wechsler, R. McDonald, M. J. Ferguson and M. Stradiotto, Chem. Commun., 2004, 2446 DOI: 10.1039/B410328A

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