Issue 19, 2004
From the journal:

Chemical Communications

A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

Philip Coppens,a   Oksana Gerlits,a   Ivan I. Vorontsov,a   Andrey Yu. Kovalevsky,a   Yu-Sheng Chen,b   Tim Graber,c   Milan Gembickya  and  Irina V. Novozhilovaa  

a Department of Chemistry, SUNY at Buffalo, Buffalo, New York, USA
E-mail: coppens@acsu.buffalo.edu
Fax: +1 716 645-6948
Tel: +1 716 645-6800

b University of Toledo, Ohio 43606, USA

c University of Chicago, Illinois 60637, USA

Abstract

A very large Rh–Rh contraction of ∼0.85 Å occurs on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion to its triplet state.

Graphical abstract: A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

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Article information

DOI
https://doi.org/10.1039/B409463H
Article type
Communication
Submitted
24 Jun 2004
Accepted
29 Jul 2004
First published
19 Aug 2004

Chem. Commun., 2004, 2144-2145

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A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction

P. Coppens, O. Gerlits, I. I. Vorontsov, A. Yu. Kovalevsky, Y. Chen, T. Graber, M. Gembicky and I. V. Novozhilova, Chem. Commun., 2004, 2144 DOI: 10.1039/B409463H

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