Issue 21, 2004
From the journal:

Chemical Communications

Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10]

Jonathan Bould,a   Yvonne M. McInnes,a   Michael J. Carra  and  John D. Kennedy*a  

* Corresponding authors

a The School of Chemistry of the University of Leeds, Leeds, England, UK, EC
E-mail: johnk@chem.leeds.ac.uk
Fax: +44 0113 343 6401
Tel: +44 0113 343 6414

Abstract

[(PMe2Ph)4Pt2B10H10] 1 reversibly takes up atmospheric dioxygen to give the fluxional dioxygen–dimetallaborane complex [(PMe2Ph)4(O2)Pt2B10H10] 2, which has Pt–Pt 2.7143(3), Pt–O 2.141(4) and 2.151(4) and O–O 1.434(6) Å.

Graphical abstract: Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10]

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Article information

DOI
https://doi.org/10.1039/B406974A
Article type
Communication
Submitted
11 May 2004
Accepted
15 Jul 2004
First published
23 Sep 2004

Chem. Commun., 2004, 2380-2381

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Metallaborane reaction chemistry. A facile and reversible dioxygen capture by a B-frame-supported bimetallic: structure of [(PMe2Ph)4(O2)Pt2B10H10]

J. Bould, Y. M. McInnes, M. J. Carr and J. D. Kennedy, Chem. Commun., 2004, 2380 DOI: 10.1039/B406974A

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