Issue 17, 2004
From the journal:

Chemical Communications

Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters†

Rebecca J. Moss,a   Kelly J. Wadsworth,a   Christopher J. Chapmana  and  Christopher G. Frost*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: c.g.frost@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386142

Abstract

The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.

Graphical abstract: Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters

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Article information

DOI
https://doi.org/10.1039/B406905F
Article type
Communication
Submitted
10 May 2004
Accepted
28 May 2004
First published
08 Jul 2004

Chem. Commun., 2004, 1984-1985

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Rhodium catalysed tandem conjugate addition-protonation: an enantioselective synthesis of 2-substituted succinic esters

R. J. Moss, K. J. Wadsworth, C. J. Chapman and C. G. Frost, Chem. Commun., 2004, 1984 DOI: 10.1039/B406905F

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