One-step synthesis of benzyl acetate by gas phase acetoxylation of toluene over highly active and selective Pd–Sb–TiO2 catalysts

A. Benhmid; K. V. Narayana; A. Martin; B. Lücke

doi:10.1039/B406396A

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One-step synthesis of benzyl acetate by gas phase acetoxylation of toluene over highly active and selective Pd–Sb–TiO₂ catalysts†

A. Benhmid,^a K. V. Narayana,^a A. Martin*^a and B. Lücke^a

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^a Institut für Angewandte Chemie Berlin-Adlershof e.V., Richard-Willstätter-Str. 12, D-12489 Berlin, Germany
E-mail: a.martin@aca-berlin.de
Fax: +49-30-63 92 44 54
Tel: +49-30-63 92 43 06

Abstract

Significantly high benzyl acetate selectivity of 85% at a toluene conversion of ca. 93% was achieved for the first time in a single step by gas phase acetoxylation over highly active and selective Pd–Sb–TiO₂ catalysts.

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Article information

DOI: https://doi.org/10.1039/B406396A
Article type: Communication
Submitted: 28 Apr 2004
Accepted: 24 Jun 2004
First published: 02 Aug 2004

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Chem. Commun., 2004, 2118-2119

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One-step synthesis of benzyl acetate by gas phase acetoxylation of toluene over highly active and selective Pd–Sb–TiO₂ catalysts

A. Benhmid, K. V. Narayana, A. Martin and B. Lücke, Chem. Commun., 2004, 2118 DOI: 10.1039/B406396A

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