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Issue 16, 2004
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A mononuclear indium(I) carbene analogue

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The ‘one pot’ reaction between K[N(SiMe3)2], InI and the β-diimine ligand precursor [H(NDippCMe)2CH] (Dipp = C6H3Pri2-2,6) gave [In{(NDippCMe)2CH}] 1, the first example of a two-coordinate, neutral, In(I) singlet ‘carbene analogue’.

Graphical abstract: A mononuclear indium(i) carbene analogue

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Publication details

The article was received on 23 Apr 2004, accepted on 08 Jun 2004 and first published on 20 Jul 2004

Article type: Communication
DOI: 10.1039/B406017B
Citation: Chem. Commun., 2004,0, 1818-1819

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    A mononuclear indium(I) carbene analogue

    M. S. Hill and P. B. Hitchcock, Chem. Commun., 2004, 0, 1818
    DOI: 10.1039/B406017B

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