Issue 17, 2004
From the journal:

Chemical Communications

A new reaction: lead(iv) acetate-mediated oxidative fragmentation of homoallylic alcohols

Marcelo D. Preite*a  and  Mauricio A. Cuellara  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Química, Pontificia Universidad Católica de Chile, Vicuña Mackenna 4860, Casilla 306, Correo-22, Chile
E-mail: mpreite@puc.cl
Fax: +[56 2] 686 4744
Tel: +[56 2] 686 4744

Abstract

Treatment of a homoallylic alcohol with lead(IV) acetate in refluxing benzene for 2 hours results in an oxidative cleavage to give a carbonyl compound and an allylic acetate with high yield.

Graphical abstract: A new reaction: lead(iv) acetate-mediated oxidative fragmentation of homoallylic alcohols

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Article information

DOI
https://doi.org/10.1039/B405986G
Article type
Communication
Submitted
21 Apr 2004
Accepted
26 May 2004
First published
09 Jul 2004

Chem. Commun., 2004, 1970-1971

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A new reaction: lead(IV) acetate-mediated oxidative fragmentation of homoallylic alcohols

M. D. Preite and M. A. Cuellar, Chem. Commun., 2004, 1970 DOI: 10.1039/B405986G

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