Issue 20, 2004
From the journal:

Chemical Communications

First asymmetric SmI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds

Murielle Chavarot,a   Michaël Rivard,a   Françoise Rose-Munch,*a   Eric Rosea  and  Sandrine Pyb  

* Corresponding authors

a Laboratoire de Chimie Organique, UMR 7611, Université P. et M. Curie, Tour 44 1er étage, BP181, 4 Place Jussieu, F-75252 Paris, France
E-mail: rosemun@ccr.jussieu.fr

b LEDSS, UMR 5616, Université J. Fourier, BP53, F-38041 Grenoble, France

Abstract

The SmI2-induced cross-coupling of Cr(CO)3-complexed nitrones with carbonyl compounds is described. This highly chemo- and diastereoselective reaction affords enantiopure β-amino alcohol complexes in excellent yields.

Graphical abstract: First asymmetric SmI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds

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Article information

DOI
https://doi.org/10.1039/B405406G
Article type
Communication
Submitted
14 Apr 2004
Accepted
24 Jun 2004
First published
07 Sep 2004

Chem. Commun., 2004, 2330-2331

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First asymmetric SmI2-induced cross-coupling of Cr(CO)3 aromatic nitrone complexes with carbonyl compounds

M. Chavarot, M. Rivard, F. Rose-Munch, E. Rose and S. Py, Chem. Commun., 2004, 2330 DOI: 10.1039/B405406G

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