Issue 17, 2004
From the journal:

Chemical Communications

Linking cyano-bridged ladders by azide to form a layered metamagnet†

Yuan-Zhu Zhang,a   Song Gao,*a   Hao-Ling Sun,a   Gang Su,b   Zhe-Ming Wanga  and  Shi-Wei Zhanga  

* Corresponding authors

a State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
E-mail: gaosong@pku.edu.cn
Fax: +86-10-62751708

b Department of Physics, The Graduate School of the Chinese Academy of Sciences, P. O. Box 3908, Beijing 100039, P. R. China

Abstract

Cyano-bridged corrugated ladder-like chains are connected by μ1,1–N3 (end-on, EO) bridges to form a layered coordination polymer, {Mn(N3)(CH3OH)[Cr(phen)(CN)4]}·CH3OH (2), which is the first mixed cyano–azide bridged compound, and shows metamagnetism below 21.8 K, a temperature much higher than that (3.4 K) of the crossed double chain [Cr(phen)(CN)4]2 [Mn(H2O)2]·4H2O (1) based on the same building block [Cr(phen)(CN)4]−.

Graphical abstract: Linking cyano-bridged ladders by azide to form a layered metamagnet

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Article information

DOI
https://doi.org/10.1039/B405167J
Article type
Communication
Submitted
07 Apr 2004
Accepted
03 Jun 2004
First published
08 Jul 2004

Chem. Commun., 2004, 1906-1907

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Linking cyano-bridged ladders by azide to form a layered metamagnet

Y. Zhang, S. Gao, H. Sun, G. Su, Z. Wang and S. Zhang, Chem. Commun., 2004, 1906 DOI: 10.1039/B405167J

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