Issue 16, 2004
From the journal:

Chemical Communications

New perspectives in hydroformylation : a para-hydrogen study†

Cyril Godard,a   Simon B. Duckett,*a   Céline Henry,a   Stacey Polas,b   Robert Tooseb  and  Adrian C. Whitwooda  

* Corresponding authors

a Department of Chemistry, University of York, Heslington, York, UK
E-mail: sbd3@york.ac.uk
Fax: +44 1904 432516

b Sasol Technology (UK) Ltd., Purdie Building, North Haugh, St Andrews, Scotland, UK

Abstract

NMR studies on the reaction of Ir(CO)(PPh3)2(η3-C3H5) with para-H2 and CO enable the complete mapping of the hydroformylation mechanism for an iridium monohydride catalyst via the detection of species which include iridium acyl and alkyl dihydride intermediates.

Graphical abstract: New perspectives in hydroformylation : a para-hydrogen study

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Article information

DOI
https://doi.org/10.1039/B404547E
Article type
Communication
Submitted
26 Mar 2004
Accepted
04 Jun 2004
First published
07 Jul 2004

Chem. Commun., 2004, 1826-1827

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New perspectives in hydroformylation : a para-hydrogen study

C. Godard, S. B. Duckett, C. Henry, S. Polas, R. Toose and A. C. Whitwood, Chem. Commun., 2004, 1826 DOI: 10.1039/B404547E

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