A robust, porous, cationic silver(I) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 49.66 net

Guang Yang; Raphael G. Raptis

doi:10.1039/B404269G

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A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 4⁹.6⁶ net†

Guang Yang^a and Raphael G. Raptis*^a

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* Corresponding authors

^a Department of Chemistry, University of Puerto Rico, Rio Piedras Campus, PO Box 23346, San Juan, PR 00931, USA
E-mail: Raphael@adam.uprr.pr
Fax: +1-787–7568242
Tel: +1-787–7640000 ext. 2598

Abstract

The reactions of silver(I) salts with 3,5-diphenyl-1,2,4-triazole result in three-dimensional, porous, cationic metal–organic frameworks based on novel 6-connected, trigonal-prismatic, pentanuclear silver-triazolate clusters, interconnected by linear N–Ag–N linkers; this robust water- and organic-insoluble structure exhibits both nonpolar-solvent adsorption and anion-exchange properties.

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Article information

DOI: https://doi.org/10.1039/B404269G
Article type: Communication
Submitted: 22 Mar 2004
Accepted: 01 Jul 2004
First published: 13 Aug 2004

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Chem. Commun., 2004, 2058-2059

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A robust, porous, cationic silver(I) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 4⁹.6⁶ net

G. Yang and R. G. Raptis, Chem. Commun., 2004, 2058 DOI: 10.1039/B404269G

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Chemical Communications