Issue 15, 2004
From the journal:

Chemical Communications

[Re6Te8(CN)6][{Ir(CO)(PPh3)2}6](OTf)2 : a new Re6 cluster-supported iridium(i) compound

Youngmee Kim,a   Sehye Kim,a   Sung-Jin Kim,*a   Myung Ki Lee,b   Mieock Kim,b   Hyungeui Leeb  and  Chong Shik Chin*b  

* Corresponding authors

a Department of Chemistry/Division of Nano Sciences, Ewha Womans University, Seoul 120-750, Korea
E-mail: sjkim@ewha.ac.kr
Fax: (+82) 2-3277-2384

b Chemistry Department, Sogang University, Mapoku Seoul 121-742, Korea
E-mail: cschin@mail.sogang.ac.kr
Fax: (+82) 2-705-8448

Abstract

A new hexanuclear rhenium cluster encapsulated by six iridium complexes, [Re6Te8(CN)6][{Ir(CO)(PPh3)2}6](OTf)2 (3), which is effective in catalyzing the hydrogenation of p-CH3C6H4C[triple bond, length as m-dash]CH to p-CH3C6H4CH[double bond, length as m-dash]CH2 has been prepared.

Graphical abstract: [Re6Te8(CN)6][{Ir(CO)(PPh3)2}6](OTf)2 : a new Re6 cluster-supported iridium(i) compound

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Article information

DOI
https://doi.org/10.1039/B403995E
Article type
Communication
Submitted
16 Mar 2004
Accepted
27 May 2004
First published
24 Jun 2004

Chem. Commun., 2004, 1692-1693

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[Re6Te8(CN)6][{Ir(CO)(PPh3)2}6](OTf)2 : a new Re6 cluster-supported iridium(I) compound

Y. Kim, S. Kim, S. Kim, M. K. Lee, M. Kim, H. Lee and C. S. Chin, Chem. Commun., 2004, 1692 DOI: 10.1039/B403995E

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