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Issue 12, 2004
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Supertetrahedral decametallic Ni(II) clusters directed by μ6-tris-alkoxides

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Abstract

We report the syntheses, structures and magnetic properties of two decametallic Ni(II) clusters with unprecedented supertetrahedral cores, stabilised by the (hitherto unobserved) μ6-coordination modes of the tris-alkoxides {MeC(CH2O)3}3− and {C6H9O3}3−.

Graphical abstract: Supertetrahedral decametallic Ni(ii) clusters directed by μ6-tris-alkoxides

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Publication details

The article was received on 16 Mar 2004, accepted on 29 Apr 2004 and first published on 17 May 2004


Article type: Communication
DOI: 10.1039/B403876B
Citation: Chem. Commun., 2004,0, 1418-1419

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    Supertetrahedral decametallic Ni(II) clusters directed by μ6-tris-alkoxides

    R. Shaw, I. S. Tidmarsh, R. H. Laye, B. Breeze, M. Helliwell, E. K. Brechin, S. L. Heath, M. Murrie, S. Ochsenbein, H. Güdel and E. J. L. McInnes, Chem. Commun., 2004, 0, 1418
    DOI: 10.1039/B403876B

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