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Issue 10, 2004
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Unprecedented copper-catalyzed asymmetric conjugate addition of organometallic reagents to α,β-unsaturated lactams

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Abstract

For the first time, an excellent enantioselectivity has been obtained in the conjugate addition of hard organometallic reagents to α,β-unsaturated lactams bearing appropriate protecting–activating groups on the nitrogen.

Graphical abstract: Unprecedented copper-catalyzed asymmetric conjugate addition of organometallic reagents to α,β-unsaturated lactams

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Publication details

The article was received on 11 Mar 2004, accepted on 06 Apr 2004 and first published on 28 Apr 2004


Article type: Communication
DOI: 10.1039/B403793F
Citation: Chem. Commun., 2004,0, 1244-1245

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    Unprecedented copper-catalyzed asymmetric conjugate addition of organometallic reagents to α,β-unsaturated lactams

    M. Pineschi, F. Del Moro, F. Gini, A. J. Minnaard and B. L. Feringa, Chem. Commun., 2004, 0, 1244
    DOI: 10.1039/B403793F

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