Iridium solutes effect C–H bond activation and C–C bond forming reactions of C6H6–MeOCH2CH2OMe solvent mixtures

Margarita Paneque; Manuel L. Poveda; Laura L. Santos; Verónica Salazar; Ernesto Carmona

doi:10.1039/B403705G

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Iridium solutes effect C–H bond activation and C–C bond forming reactions of C₆H₆–MeOCH₂CH₂OMe solvent mixtures†

Margarita Paneque,*^a Manuel L. Poveda,^a Laura L. Santos,^a Verónica Salazar^b and Ernesto Carmona*^a

Author affiliations

* Corresponding authors

^a Instituto de Investigaciones Químicas, CSIC-Universidad de Sevilla, Avda. Américo Vespucio s/n, Isla de la Cartuja, 41092 Sevilla, Spain
E-mail: guzman@us.es
Fax: 34 954460565
Tel: 34 954489558

^b CIQ, Universidad Autónoma del Estado de Hidalgo, Pachuca, Hidalgo, México

Abstract

The in situ generated [Tp^Me2Ir(C₆H₅)₂] fragment induces both aromatic and aliphatic C–H bond activation reactions, along with C–C bond formation, when heated with benzene and 1,2-dimethoxyethane.

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Article information

DOI: https://doi.org/10.1039/B403705G
Article type: Communication
Submitted: 11 Mar 2004
Accepted: 18 Jun 2004
First published: 23 Jul 2004

Download Citation

Chem. Commun., 2004, 1838-1839

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Iridium solutes effect C–H bond activation and C–C bond forming reactions of C₆H₆–MeOCH₂CH₂OMe solvent mixtures

M. Paneque, M. L. Poveda, L. L. Santos, V. Salazar and E. Carmona, Chem. Commun., 2004, 1838 DOI: 10.1039/B403705G

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Chemical Communications