Issue 12, 2004
From the journal:

Chemical Communications

Iron-catalysed propylene epoxidation by nitrous oxide: dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

Xiaoxing Wang,a   Qinghong Zhang,a   Qian Guo,a   Yinchuan Lou,a   Lüjuan Yanga  and  Ye Wang*a  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, P. R. China
E-mail: yewang@jingxian.xmu.edu.cn
Fax: (+86)-592-2183047
Tel: (+86)-592-2187470

Abstract

A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N2O when the FeOx/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N2O.

Graphical abstract: Iron-catalysed propylene epoxidation by nitrous oxide: dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

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Article information

DOI
https://doi.org/10.1039/B402839B
Article type
Communication
Submitted
24 Feb 2004
Accepted
15 Apr 2004
First published
14 May 2004

Chem. Commun., 2004, 1396-1397

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Iron-catalysed propylene epoxidation by nitrous oxide: dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

X. Wang, Q. Zhang, Q. Guo, Y. Lou, L. Yang and Y. Wang, Chem. Commun., 2004, 1396 DOI: 10.1039/B402839B

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