Highly efficient Pauson–Khand reaction with C60: regioselective synthesis of unprecedented cis-1 biscycloadducts

Nazario Martín; Margarita Altable; Salvatore Filippone; Ángel Martín-Domenech

doi:10.1039/B402616K

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Highly efficient Pauson–Khand reaction with C₆₀: regioselective synthesis of unprecedented cis-1 biscycloadducts†

Nazario Martín,*^a Margarita Altable,^a Salvatore Filippone^a and Ángel Martín-Domenech^a

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* Corresponding authors

^a Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, E-28040 Madrid, Spain
E-mail: nazmar@quim.ucm.es
Fax: 0034 913944103
Tel: 0034 913944227

Abstract

Fullerenes undergo regioselectively and highly efficiently the intramolecular Pauson–Khand reaction to afford a new type of unprecedented structure with three fused pentagonal rings on the same fullerene six-membered ring.

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Article information

DOI: https://doi.org/10.1039/B402616K
Article type: Communication
Submitted: 20 Feb 2004
Accepted: 02 Apr 2004
First published: 04 May 2004

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Chem. Commun., 2004, 1338-1339

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Highly efficient Pauson–Khand reaction with C₆₀: regioselective synthesis of unprecedented cis-1 biscycloadducts

N. Martín, M. Altable, S. Filippone and Á. Martín-Domenech, Chem. Commun., 2004, 1338 DOI: 10.1039/B402616K

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