Issue 8, 2004
From the journal:

Chemical Communications

Solvent-free ketone hydrogenations catalyzed by molybdenum complexes†

Barbara F. M. Kimmich,a   Paul J. Fagan,b   Elisabeth Hauptmanb  and  R. Morris Bullock*a  

* Corresponding authors

a Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973, USA
E-mail: bullock@bnl.gov
Fax: (+1) 631 344-5815

b Central Research and Development Department, The DuPont Company, Experimental Station, P.O. Box 80328, Wilmington, Delaware 19880, USA

Abstract

Et2C[double bond, length as m-dash]O is hydrogenated under solvent-free conditions using a catalyst prepared by hydride abstraction from HMo(CO)2[η5:η1-C5H4(CH2)2PCy2]; the catalyst functions at low catalyst loadings (<0.4 mol%).

Graphical abstract: Solvent-free ketone hydrogenations catalyzed by molybdenum complexes

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Article information

DOI
https://doi.org/10.1039/B401760A
Article type
Communication
Submitted
04 Feb 2004
Accepted
23 Feb 2004
First published
22 Mar 2004

Chem. Commun., 2004, 1014-1015

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Solvent-free ketone hydrogenations catalyzed by molybdenum complexes

B. F. M. Kimmich, P. J. Fagan, E. Hauptman and R. M. Bullock, Chem. Commun., 2004, 1014 DOI: 10.1039/B401760A

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