Issue 9, 2004
From the journal:

Chemical Communications

Two mixed-valence copper(i,ii) imidazolate coordination polymers: metal-valence tuning approach for new topological structures†

Xiao-Chun Huang,ab   Jie-Peng Zhang,a   Yan-Yong Lin,a   Xiao-Lan Yua  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: cescxm@zsu.edu.cn
Fax: +86 20 8411-2245

b Department of Chemistry, Shantou University, Shantou, Guangdong 515063, China

Abstract

A new metal-valence tuning synthetic approach has been utilized to generate two new mixed-valence Cu(I,II) coordination polymers Cu2(im)3 and Cu3(im)4 (Him = imidazole), which are an unprecedented uninodal 4-connected 4.85 topological net and a 4-connected (4,4) net, respectively.

Graphical abstract: Two mixed-valence copper(i,ii) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

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Article information

DOI
https://doi.org/10.1039/B401691B
Article type
Communication
Submitted
04 Feb 2004
Accepted
10 Mar 2004
First published
01 Apr 2004

Chem. Commun., 2004, 1100-1101

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Two mixed-valence copper(I,II) imidazolate coordination polymers: metal-valence tuning approach for new topological structures

X. Huang, J. Zhang, Y. Lin, X. Yu and X. Chen, Chem. Commun., 2004, 1100 DOI: 10.1039/B401691B

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