Issue 9, 2004
From the journal:

Chemical Communications

A novel ligand-unsupported 3D framework polymer of trimeric copper(i)) and its NLO property

Yao Kang,a   Yuan-Gen Yao,*a   Ye-Yan Qin,a   Jian Zhang,a   Yu-Biao Chen,a   Zhao-Ji Li,a   Yi-Hang Wen,a   Jian-Kai Chenga  and  Rui-Feng Hua  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China
E-mail: yyg@ms.fjirsm.ac.cn

Abstract

A novel 3-D coordination polymer with trimeric copper (I) unit, [Cu3(CN)(IN)2]n (IN = isonicotinate), was hydrothermally synthesized by the reaction of Cu(NO3)2·3H2O with isonicotinic and terephthalic acids. The structure was characterized to be a twofold interpenetrated 3-D coordination network polymer with two-coordinated copper(I). It has a powder SHG efficiency about that of KDP.

Graphical abstract: A novel ligand-unsupported 3D framework polymer of trimeric copper(i)) and its NLO property

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Article information

DOI
https://doi.org/10.1039/B401345J
Article type
Communication
Submitted
28 Jan 2004
Accepted
17 Mar 2004
First published
05 Apr 2004

Chem. Commun., 2004, 1046-1047

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A novel ligand-unsupported 3D framework polymer of trimeric copper(I)) and its NLO property

Y. Kang, Y. Yao, Y. Qin, J. Zhang, Y. Chen, Z. Li, Y. Wen, J. Cheng and R. Hu, Chem. Commun., 2004, 1046 DOI: 10.1039/B401345J

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