Issue 10, 2004
From the journal:

Chemical Communications

A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate†

Cristina Carcedo,a   Athanasia Dervisi,*a   Ian A. Fallis,a   Liling Ooia  and  K. M. Abdul Malika  

* Corresponding authors

a Department of Chemistry, Cardiff University, PO Box 912, Cardiff
E-mail: dervisia@cardiff.ac.uk
Fax: 029 20874030
Tel: 029 20874081

Abstract

The synthesis of the novel C2-symmetric diphosphine 1,4:3,6-dianhydro-2,5-bis(diphenylphosphino)-D-mannitol (ddppm) from D-isomannide is reported and its performance in asymmetric hydrogenations discussed.

Graphical abstract: A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

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Article information

DOI
https://doi.org/10.1039/B401301H
Article type
Communication
Submitted
29 Jan 2004
Accepted
06 Apr 2004
First published
27 Apr 2004

Chem. Commun., 2004, 1236-1237

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A concise synthesis of a rigid isomannide-based diphosphine ligand and structural characterisation of an alkoxyphosphonium intermediate

C. Carcedo, A. Dervisi, I. A. Fallis, L. Ooi and K. M. A. Malik, Chem. Commun., 2004, 1236 DOI: 10.1039/B401301H

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