Issue 8, 2004
From the journal:

Chemical Communications

Synthesis of the first enantiomerically pure and chiral, disubstituted 3,4-ethylenedioxythiophenes (EDOTs) and corresponding stereo- and regioregular PEDOTs

Dolores Caras-Quinteroa  and  Peter Bäuerle*a  

* Corresponding authors

a Department of Organic Chemistry II (Organic Materials and Combinatorial Chemistry), University of Ulm, Albert-Einstein-Allee 11, Ulm, Germany
E-mail: peter.baeuerle@chemie.uni-ulm.de
Fax: +49-731-50-22840
Tel: +49-731-22250

Abstract

Novel disubstituted EDOT monomers were synthesized in good yields from 3,4-dimethoxythiophene and (chiral) glycols by transetherification. The stereochemistry of the monomers affects the electronic properties of the corresponding chiral PEDOT derivatives.

Graphical abstract: Synthesis of the first enantiomerically pure and chiral, disubstituted 3,4-ethylenedioxythiophenes (EDOTs) and corresponding stereo- and regioregular PEDOTs

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Article information

DOI
https://doi.org/10.1039/B400965G
Article type
Communication
Submitted
20 Jan 2004
Accepted
17 Feb 2004
First published
11 Mar 2004

Chem. Commun., 2004, 926-927

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Synthesis of the first enantiomerically pure and chiral, disubstituted 3,4-ethylenedioxythiophenes (EDOTs) and corresponding stereo- and regioregular PEDOTs

D. Caras-Quintero and P. Bäuerle, Chem. Commun., 2004, 926 DOI: 10.1039/B400965G

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