Issue 7, 2004
From the journal:

Chemical Communications

Ti–Mo heterobimetallic thiacalix[4]arene complex containing an unusual α-agostic μ2-η5:η2-cyclopentadienyl ligand

Shin Takemoto,†b   Shinpei Tanaka,a   Yasushi Mizobeb  and  Masanobu Hidai*a  

* Corresponding authors

a Department of Materials Science and Technology, Faculty of Industrial Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510, Japan
E-mail: hidai@rs.noda.tus.ac.jp

b Institute of Industrial Science, The University of Tokyo, Komaba, Tokyo 153-8505, Japan

Abstract

A stepwise reaction of p-tert-butylthiacalix[4]arene (TC4A–(OH)4) with [CpTiCl3]–NEt3 and cis-[Mo(N2)2(PMe2Ph)4] afforded a new Ti–Mo heterobimetallic complex [TC4A–(O)4Ti(μ2-C5H5)MoH(PMe2Ph)2] which shows an unusual α-agostic μ2-η5:η2-coordination of a cyclopentadienyl ligand.

Graphical abstract: Ti–Mo heterobimetallic thiacalix[4]arene complex containing an unusual α-agostic μ2-η5:η2-cyclopentadienyl ligand

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Article information

DOI
https://doi.org/10.1039/B316972C
Article type
Communication
Submitted
06 Jan 2004
Accepted
03 Feb 2004
First published
26 Feb 2004

Chem. Commun., 2004, 838-839

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Ti–Mo heterobimetallic thiacalix[4]arene complex containing an unusual α-agostic μ2-η5:η2-cyclopentadienyl ligand

S. Takemoto, S. Tanaka, Y. Mizobe and M. Hidai, Chem. Commun., 2004, 838 DOI: 10.1039/B316972C

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