Issue 6, 2004
From the journal:

Chemical Communications

A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

Muralee Murugesu,a   Philippa King,a   Rodolphe Clérac,b   Christopher E. Ansona  and  Annie K. Powell*a  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Karlsruhe, Engessserstr. Geb. 30.45, D-76128 Karlsruhe, Germany
E-mail: powell@chemie.uni-karlsruhe.de

b Centre de Recherche Paul Pascal, CNRS UPR-8641, 115 Avenue Dr. A. Schweitzer, 33600 Pessac, France

Abstract

The CuII aggregate in [Cu9(cpida)6(MeOH)6]ยท6(MeOH) {H3cpida = 2-(carboxyphenyl)iminodiacetic acid} is made up of two weakly ferromagnetically coupled carboxylate-bridged Cu4 units that are antiferromagnetically linked through a central CuII to give a Cu9 core with an S = 7/2 spin ground state.

Graphical abstract: A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

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Article information

DOI
https://doi.org/10.1039/B316233H
Article type
Communication
Submitted
11 Dec 2003
Accepted
26 Jan 2004
First published
23 Feb 2004

Chem. Commun., 2004, 740-741

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A novel nonanuclear CuII carboxylate-bridged cluster aggregate with an S = 7/2 ground spin state

M. Murugesu, P. King, R. Clérac, C. E. Anson and A. K. Powell, Chem. Commun., 2004, 740 DOI: 10.1039/B316233H

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