Ring selectivity and migratory aptitude of Cp*Ru+ complexation to acecorannulene

T. Jon Seiders; Kim K. Baldridge; Joseph M. O'Connor; Jay S. Siegel

doi:10.1039/B316061K

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Ring selectivity and migratory aptitude of Cp*Ru⁺ complexation to acecorannulene†

T. Jon Seiders,^a Kim K. Baldridge,^abc Joseph M. O'Connor^a and Jay S. Siegel*^ac

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* Corresponding authors

^a Department of Chemistry, University of California, San Diego, CA 92093-0358, USA

^b San Diego Supercomputer Center, P.O. Box 85608, San Diego, CA 92186-9784, USA

^c Organisch-chemisches Institut, Universität Zürich, Zürich, CH-8057, Switzerland

Abstract

Synthesis and spectral characterization of acecorannulene CpRu⁺ complexes, in combination with ab initio quantum chemical computations, leads to the hypothesis that η⁶-metal binding prefers the exo face in the region of least curvature.

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Supplementary files

Experimental details DOC (29K)

Article information

DOI: https://doi.org/10.1039/B316061K
Article type: Communication
Submitted: 08 Dec 2003
Accepted: 21 Jan 2004
First published: 12 Mar 2004

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Chem. Commun., 2004, 950-951

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Ring selectivity and migratory aptitude of Cp*Ru⁺ complexation to acecorannulene

T. J. Seiders, K. K. Baldridge, J. M. O'Connor and J. S. Siegel, Chem. Commun., 2004, 950 DOI: 10.1039/B316061K

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