Issue 6, 2004
From the journal:

Chemical Communications

Platinum(ii)-bis(9-methyladenine) complexes; N1→N6 migration of Pt(ii) vsdeamination of coordinated methyladenine†

Karel D. Klika*a  and  Jorma Arpalahtia  

* Corresponding authors

a Department of Chemistry, University of Turku, FIN–20014 Turku, Finland
E-mail: karel.klika@utu.fi
Fax: 358 (2) 333-6700
Tel: 358 (2) 333-6762

Abstract

Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N1) complex of cis-PtII(NH3)2 in basic solution, whereafter deamination of the 9-methyladenine still coordinated at N-1 competes with a second migration step.

Graphical abstract: Platinum(ii)-bis(9-methyladenine) complexes; N1→N6 migration of Pt(ii) vs deamination of coordinated methyladenine

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Article information

DOI
https://doi.org/10.1039/B315987F
Article type
Communication
Submitted
08 Dec 2003
Accepted
08 Jan 2004
First published
10 Feb 2004

Chem. Commun., 2004, 666-667

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Platinum(II)-bis(9-methyladenine) complexes; N1→N6 migration of Pt(II) vs deamination of coordinated methyladenine

K. D. Klika and J. Arpalahti, Chem. Commun., 2004, 666 DOI: 10.1039/B315987F

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