Issue 6, 2004

Protonic modulation of redox properties in ionisable [2 × 2] grid-like metalloarrays

Abstract

The oxidation state of the cobalt centres can be controlled by modification of the protonation state in [2 × 2] grid-like arrays based on ionisable bis(hydrazone) ligands, allowing conversion of the paramagnetic CoII4 into the diamagnetic CoIII4 grid.

Graphical abstract: Protonic modulation of redox properties in ionisable [2 × 2] grid-like metalloarrays

Supplementary files

Article information

Article type
Communication
Submitted
26 Nov 2003
Accepted
21 Jan 2004
First published
12 Feb 2004

Chem. Commun., 2004, 718-719

Protonic modulation of redox properties in ionisable [2 × 2] grid-like metalloarrays

L. H. Uppadine, J. Gisselbrecht and J. Lehn, Chem. Commun., 2004, 718 DOI: 10.1039/B315352E

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