Issue 4, 2004
From the journal:

Chemical Communications

Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides†

Vesela Ugrinova,a   Gregory A. Ellisa  and  Seth N. Brown*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, Indiana 46556-5670, U. S. A.
E-mail: Seth.N.Brown.114@nd.edu
Fax: +1 574 631 6652
Tel: +1 574 631 4659

Abstract

The monomeric titanium(IV) hydroxide complex, LTi(OH) (LH3 = tris(2-hydroxy-3,5-di-tert-butylbenzyl)amine), which is sterically inhibited from condensation to a μ-oxo dimer, cannot be prepared by hydrolysis of the alkoxide, with Keq = 0.012 for hydrolysis of the titanium methoxide in THF.

Graphical abstract: Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides

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Article information

DOI
https://doi.org/10.1039/B315092E
Article type
Communication
Submitted
20 Nov 2003
Accepted
08 Dec 2003
First published
22 Jan 2004

Chem. Commun., 2004, 468-469

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Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides

V. Ugrinova, G. A. Ellis and S. N. Brown, Chem. Commun., 2004, 468 DOI: 10.1039/B315092E

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