Issue 5, 2004

The kinetics of propene and hexenepolymerisation with [(SBI)ZrR]+X: evidence for monomer-dependent early or late transition states

Abstract

Whereas the rates of propene polymerisation catalysed by zirconocene ion pairs are strongly anion-dependent, hexene polymerisations are not; the findings demonstrate the existence of very different kinetic regimes for two closely related reactions.

Graphical abstract: The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X−: evidence for monomer-dependent early or late transition states

Supplementary files

Article information

Article type
Communication
Submitted
18 Nov 2003
Accepted
08 Jan 2004
First published
05 Feb 2004

Chem. Commun., 2004, 542-543

The kinetics of propene and hexene polymerisation with [(SBI)ZrR]+X: evidence for monomer-dependent early or late transition states

F. Song, R. D. Cannon and M. Bochmann, Chem. Commun., 2004, 542 DOI: 10.1039/B314845A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements