Issue 4, 2004

Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

Abstract

The reaction of 1,3-dimesitylimidazolium chloride with Ti(NMe2)4 results in the 1,3-dimesitylimadazol-2-ylidene complex of Ti(NMe2)2Cl2 (3); the X-ray crystal structure of 3 evidences short intramolecular Cl⋯Ccarbene contacts.

Graphical abstract: Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov 2003
Accepted
27 Nov 2003
First published
15 Jan 2004

Chem. Commun., 2004, 360-361

Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

P. Shukla, J. A. Johnson, D. Vidovic, A. H. Cowley and C. D. Abernethy, Chem. Commun., 2004, 360 DOI: 10.1039/B314558A

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