C1 Coupling via bromine activation and tandem catalytic condensation and neutralization over CaO/zeolite composites

Ivan Lorkovic; Maria Noy; Mike Weiss; Jeff Sherman; Eric McFarland; Galen D. Stucky; Peter C. Ford

doi:10.1039/B314118G

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C₁ Coupling via bromine activation and tandem catalytic condensation and neutralization over CaO/zeolite composites†

Ivan Lorkovic,*^a Maria Noy,^a Mike Weiss,^b Jeff Sherman,^b Eric McFarland,^bc Galen D. Stucky^a and Peter C. Ford^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106
E-mail: lorkovic@chem.ucsb.edu
Fax: +1 805 893 4120
Tel: +1 805 893 5239

^b Gas Reaction Technogies, Inc., 301B S. Wimbrow Dr. Sebastian, FL 32958

^c Department of Chemical Engineering, University of California, Santa Barbara, CA 93106

Abstract

We demonstrate here an alternative scheme for C₁ coupling by way of methane bromination, followed by concurrent bromomethane condensation and quantitative HBr neutralization; regeneration of the metal oxide with O₂ with recovery of Br₂ completes the cycle.

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Article information

DOI: https://doi.org/10.1039/B314118G
Article type: Communication
Submitted: 05 Nov 2003
Accepted: 23 Dec 2003
First published: 06 Feb 2004

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Chem. Commun., 2004, 566-567

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C₁ Coupling via bromine activation and tandem catalytic condensation and neutralization over CaO/zeolite composites

I. Lorkovic, M. Noy, M. Weiss, J. Sherman, E. McFarland, G. D. Stucky and P. C. Ford, Chem. Commun., 2004, 566 DOI: 10.1039/B314118G

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