Issue 4, 2004
From the journal:

Chemical Communications

Synthesis and properties of a new class of nitrogen-rich multinuclear[m.n] ferrocenophanes†

Alberto Tárraga,*a   Francisco Otón,a   Arturo Espinosa,a   M. Desamparados Velasco,a   Pedro Molina*b  and  David J. Evansa  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, Murcia, Spain
E-mail: pmolina@um.es

b Department of Biological Chemistry, John Innes Centre, Norwich Research Park, Colney, Norwich, UK

Abstract

The synthesis of the first tetraaza[3,3]ferrocenophane, from the previously unreported 1,1′-bis(triphenylphosphoranylidenamino)ferrocene and its conversion into a nitrogen-rich [2,2]bis[3,3]ferrocenophane is described. The electronic behaviour of these multinuclear ferrocenophanes indicates a strong electronic coupling between the iron centers.

Graphical abstract: Synthesis and properties of a new class of nitrogen-rich multinuclear[m.n] ferrocenophanes

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Article information

DOI
https://doi.org/10.1039/B313797J
Article type
Communication
Submitted
31 Oct 2003
Accepted
20 Nov 2003
First published
11 Dec 2003

Chem. Commun., 2004, 458-459

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Synthesis and properties of a new class of nitrogen-rich multinuclear[m.n] ferrocenophanes

A. Tárraga, F. Otón, A. Espinosa, M. Desamparados Velasco, P. Molina and D. J. Evans, Chem. Commun., 2004, 458 DOI: 10.1039/B313797J

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