Issue 6, 2004
From the journal:

Chemical Communications

Isolation, dynamic NMR study and X-ray characterisation of a bis sulfonium zirconocene-ate dimer†

Esteban Ortega,a   Nadine Pirio,a   Philippe Meunier*a  and  Bruno Donnadieub  

* Corresponding authors

a Laboratoire de Synthèse et Electrosynthèse Organométalliques associé au CNRS (UMR 5188), Université de Bourgogne, Faculté des Sciences Gabriel, 6 boulevard Gabriel, 21000 Dijon, France
E-mail: Philippe.Meunier@u-bourgogne.fr
Fax: +33(0)380396100
Tel: +33(0)380396105

b Laboratoire de Chimie de coordination du CNRS (UPR 8241), 205 route de Narbonne, 31077 Toulouse cedex 4, France

Abstract

The novel dimer [Cp2Zr[upper bond 1 start]⊖S⊕CH(Ph)CH[double bond, length as m-dash]C[upper bond 1 end]PPh2]2, the first example of a structurally characterised sulfur-bridged binuclear zirconathiolane complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some aspects of its solution behaviour were studied.

Graphical abstract: Isolation, dynamic NMR study and X-ray characterisation of a bis sulfonium zirconocene-ate dimer

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Article information

DOI
https://doi.org/10.1039/B312954C
Article type
Communication
Submitted
15 Oct 2003
Accepted
09 Jan 2004
First published
11 Feb 2004

Chem. Commun., 2004, 678-679

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Isolation, dynamic NMR study and X-ray characterisation of a bis sulfonium zirconocene-ate dimer

E. Ortega, N. Pirio, P. Meunier and B. Donnadieu, Chem. Commun., 2004, 678 DOI: 10.1039/B312954C

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