Issue 6, 2004
From the journal:

Chemical Communications

A helical array of pendant fullerenes on a helical poly(phenylacetylene) induced by non-covalent chiral interactions†

Tatsuya Nishimura,a   Sousuke Ohsawa,a   Katsuhiro Maedaa  and  Eiji Yashima*a  

* Corresponding authors

a Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan
E-mail: yashima@apchem.nagoya-u.ac.jp

Abstract

Novel [60]fullerene-based poly(phenylacetylene)s prepared by the copolymerization of achiral phenylacetylenes bearing a C60 or crown ether pendant form a one-handed helix upon complexation with L- and D-alanine, yielding a helical array of the pendant fullerenes with a predominant screw-sense along the polymer backbone.

Graphical abstract: A helical array of pendant fullerenes on a helical poly(phenylacetylene) induced by non-covalent chiral interactions

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Article information

DOI
https://doi.org/10.1039/B312511D
Article type
Communication
Submitted
08 Oct 2003
Accepted
27 Jan 2004
First published
10 Feb 2004

Chem. Commun., 2004, 646-647

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A helical array of pendant fullerenes on a helical poly(phenylacetylene) induced by non-covalent chiral interactions

T. Nishimura, S. Ohsawa, K. Maeda and E. Yashima, Chem. Commun., 2004, 646 DOI: 10.1039/B312511D

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